The effect of thermal treatment on the 57Fe Mössbauer spectrum of beryl     

Geraldo Magela da Costa  Gabriel de Oliveira Polli  Márcio A. Kahwage  Eddy de Grave  Antônio Claret Soares Sabioni  Júlio Cesar Mendes 《Physics and Chemistry of Minerals》2006,33(3):161-166

Mössbauer spectra (MS) of blue, green and yellow beryl (ideally Be₃Al₂Si₆O₁₈) containing approximately 1% of iron were obtained at 295 and 500 K. Room temperature (RT) spectra of both blue and green samples showed the presence of an asymmetric Fe²⁺ doublet (ΔE _Q~2.7 mm/s, δ~1.1 mm/s), with a very broad low-velocity peak. There is no clear evidence for the presence of a ferric component. The MS of the yellow sample at RT consists of an intense central absorption with parameters typical for Fe³⁺ (ΔE _Q~0.4 mm/s, δ~0.29 mm/s), plus an apparently symmetrical Fe²⁺ doublet. This sample acquires a light-blue shade upon heating in air at about 620 K. Thermal treatments at high temperatures caused no significant changes in the MS, but the green and yellow beryl acquire a blue colour. All these results are interpreted in relation to the existence of channel water and the distribution of iron among the available crystallographic sites.  相似文献   

The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt   总被引：4，自引：0，他引：4  

J. Sánchez España  E. López Pamo  E. Santofimia Pastor  J. Reyes Andrés  J. A. Martín Rubí 《Aquatic Geochemistry》2006,12(3):269-298

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.  相似文献   

Avalanche Risk During Backcountry Skiing – An Analysis of Risk Factors     

Harpa Grímsdóttir  David Mcclung 《Natural Hazards》2006,39(1):127-153

Skier-triggered avalanches are the main cause of avalanche accidents in backcountry skiing. The risk of accidents during backcountry skiing was analysed statistically and related to factors such as elevation level, aspect, stability rating and the time of the year. The analysis is based on a database about terrain usage and avalanche accidents from a large heli-skiing operator in Canada, which makes it possible to study the conditional probability of accidents given the recorded pattern of terrain usage. This study shows that the historical risk of accidentally triggering an avalanche greater than size 1 depends highly on the stability rating, with the highest risk occurring during “poor” stability. The risk is greater at high elevations, and it is lower during the late season than earlier on. Skier risk does not depend as much on aspect as may be indicated from avalanche data alone. However, it is relatively high in the N–NE–E sector. These factors are not independent of each other and therefore analyses of combined factors were also performed. Questionnaires and interviews were used to gain knowledge about the terrain selection of professional mountain guides. These results indicate that when selecting terrain, guides first look at the overall shape and size of the terrain, but avalanche history of terrain and inclination are also important factors. Finally, remarks in avalanche reports were analysed, and common human factors identified.  相似文献   

IAG Newsletter     

Gyula Tóth 《Journal of Geodesy》2005,78(10):637-644

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Geochemistry of Coexisting Biotite and Muscovite of Portuguese Peraluminous Granitic Differentiation Series     

A.M.R. Neiva  M.M.V.G. Silva  M.E.P. Gomes  T.F.C. Campos 《Chemie der Erde / Geochemistry》2002,62(3):197-215

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Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition     

G. M. da Costa  E. Van San  E. De Grave  R. E. Vandenberghe  V. Barrón  L. Datas 《Physics and Chemistry of Minerals》2002,29(2):122-131

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.  相似文献   

Spatial and temporal variation of the nekton and hyperbenthos from a temperate European estuary with regulated freshwater inflow     

Pilar Drake  Alberto M. Arias  Francisco Baldó  José A. Cuesta  Antonio Rodríguez  Alfonso Silva-Garcia  Ignacio Sobrino  Diego García-González  Carlos Fernández-Delgado 《Estuaries and Coasts》2002,25(3):451-468

The aquatic macrofauna of the Guadalquivir estuary were sampled (1 mm mesh persiana net) at 5 sampling sites located along the entire (except the tidal freshwater region) estuarine gradient of salinity (outer 50 km). A total of 134 fish and macroinvertebrate species was collected but only 62 were considered common or regularly present in the estuary. Univariate measures of the community structure showed statistically significant differences among sampling sites: species richness, abundance, and biomass decreased in the upstream direction, being positively correlated with the salinity. Temporal differences of these three variables were also statistically significant. While a clear seasonal pattern (minimum densities in winter and maximum in spring-summer) was observed for abundance and biomass, no such pattern existed for the number of species. Mysids was the most dominant group throughout the estuary (96% to 99% of abundance; 49% to 85% of biomass), although fish biomass was also important at the outer estuary (36% to 38%). Multivariate analyses indicated highly significant spatial variation in the macrofaunal communities observed along the salinity gradient. These analyses suggest that the underlying structure was a continuum with more or less overlapping distributions of the species dependent on their ability to tolerate different physicochemical conditions. There were also significant temporal (intermonthly + interannual) variation of the estuarine community; the relative multivariate dispersion indicated that monthly variation was more considerable (relative multivariate dispersion >1) at the outer part of the estuary during the wet year (last 20 km) and was higher in the inner stations during the dry year (32 to 50 km from the river mouth). Since a clear negative exponential relationship was observed between the freshwater input (from a dam located 110 km upstream) and water salinity at all sampling stations, it is concluded that the human freshwater management is probably affecting the studied estuarine communities. While the higher seasonal (long-term) stability of the salinity gradient, due to the human control of the freshwater input, may facilitate the recruitment of marine species juveniles during the meteorologically unstable early-spring, the additional (short-term) salinity fluctuations during the warm period may negatively affect species that complete their lifecycle within the estuary.  相似文献   

An estuarine benthic index of biotic integrity for the Mid-Atlantic region of the United States. II. Index development     

Roberto J. Llansó  Lisa C. Scott  Jeffrey L. Hyland  Daniel M. Dauer  David E. Russell  Frederick W. Kutz 《Estuaries and Coasts》2002,25(6):1231-1242

A benthic index of biotic integrity was developed for use in estuaries of the mid-Atlantic region of the United States (Delaware Bay estuary through Albemarle-Pamlico Sound). The index was developed for the Mid-Atlantic Integrated Assessment Program (MAIA) of the U.S. Environmental Protection Agency using procedures similar to those applied previously in Chesapeake Bay and southeastern estuaries, and was based on sampling in July through early October. Data from seven federal and state sampling programs were used to categorize sites as degraded or non-degraded based on dissolved oxygen, sediment contaminant, and sediment toxicity criteria. Various metrics of benthic community structure and function that distinguished between degraded and reference (non-degraded) sites were selected for each of five major habitat types defined by classification analysis of assemblages. Each metric was scored according to thresholds established on the distribution of values at reference sites, so that sites with low scoring metrics would be expected to show signs of degradation. For each habitat, metrics that correctly classified at least 50% of the degraded sites in the calibration data set were selected whenever possible to derive the index. The final index integrated the average score of the combination of metrics that performed best according to several criteria. Selected metrics included measures of productivity (abundance), diversity (number of taxa, Shannon-Wiener diversity, percent dominance), species composition and life history (percent abundance of pollution-indicative taxa, percent abundance of pollution-sensitive taxa, percent abundance of Bivalvia, Tanypodinae-Chironomidae abundance ratio), and trophic composition (percent abundance of deep-deposit feeders). The index correctly classified 82% of all sites in an independent data set. Classification efficiencies of sites were higher in the mesohaline and polyhaline habitats (81–92%) than in the oligohaline (71%) and the tidal freshwater (61%). Although application of the index to low salinity habitats should be done with caution, the MAIA index appeared to be quite reliable with a high likelihood of correctly identifying both degraded and non-degraded conditions. The index is expected to be of great utility in regional assessments as a tool for evaluating the integrity of benthic assemblages and tracking their condition over time.  相似文献   

Seismic Hazard Estimate at the Iberian Peninsula   总被引：1，自引：0，他引：1  

J. A. Peláez Montilla  C. López Casado 《Pure and Applied Geophysics》2002,159(11-12):2699-2713

—?Seismic hazard at the Iberian Peninsula has been evaluated by using a methodology which combines both zonified and non-zonified probabilistic methods. Seismic sources are used when considering zones where certain calculation parameters may be considered homogeneous, as in zonified methods, while, on the other hand, earthquakes are considered wherever it has taken place, as in non-zonified methods. The methodology which is applied in this paper has been originally used to calculate the seismic hazard maps in the United States. In our case, it has been necessary to adapt the method to the specific features of the seismicity in the Iberian Peninsula and its geographical surroundings, not only with respect to its distribution and characteristics, but also with respect to the properties of the seismic catalog used.¶Geographically, the main feature of the result is the fact that it reflects both historical seismicity and current seismic clusters of the region. Despite the smoothing, maps show marked differences between several seismic zones; these differences becoming more noticeable as exposure time increases. Maximum seismic hazard is found to be in the southwestern region of the Peninsula, especially in the area of the Cape St. Vicent, and around Lisbon. The uncertainty of the results, without considering that due to the attenuation laws, as deduced from the other evaluation parameters, is quite stable, being more sensitive to the parameters b and m _max of the Gutenberg-Richter relation.  相似文献   

Rock magnetic evidence of inflation of a flood basalt lava flow     

Edgardo Cañón-Tapia  Robert Coe 《Bulletin of Volcanology》2002,64(5):289-302

The anisotropy of magnetic susceptibility (AMS) of lava flows is an innovative method which has been proved to be directly related to the shear history of lava. One of the advantages of this method is that it can be used in the absence of other morphological features commonly employed to study the mechanism of emplacement of lava flows. This feature of the AMS method makes it very attractive to gain insight into the mechanism of emplacement of massive, relatively featureless, long lava flows such as those forming flood basalt provinces. In this work, we report the results of the measurement of AMS as a function of vertical position within the Birkett lava flow, one of the Columbia River Basalt Group flows. The observed variation of AMS allows us to identify at least 16 discrete events of lava injection and to estimate the thickness of individual injection events. The AMS-estimated thickness of each injection event (in the range of 0.5-4.0 m) coincides with the range inferred for injected lava pulses in modern Hawaiian lava flows. Thus, the evidence provided by the AMS method supports the notion that at least some flood basalt lava flows were emplaced by the same mechanism as many present-day inflated pahoehoe flows. Regarding the orientation of the principal susceptibilities, in the central part of the flow they define a preferred orientation along an E-W trend, whereas in the outer parts of the flow they have a NNE-SSW trend. This difference in the orientation of the principal susceptibilities is interpreted as the result of a change of flow direction of the lava as emplacement progressed. Electronic supplementary material to this paper can be obtained by using the Springer LINK server located at http://dx.doi.org/10.1007/s00445-002-0203-8.  相似文献